Led by former England all-rounder Andrew Flintoff, who is on his first tour as Lions head coach, the backroom team also includes former England spinner Graeme Swann and former South Africa internationals Dale Steyn and Neil McKenzie.
The team left on Wednesday for a training camp that will focus in part on white-ball skills and ends with a four-day match against South Africa A.
At the same time, Taylor will also work with a Young Lions U19 team in South Africa. This group includes Flintoff's son Rocky and Archie Vaughan, son of former England captain Michael.
In 2013, Taylor held talks about playing for the Sussex men's second eleven, although he never featured in a game.
Taylor made history in 2015 when she became the first woman to play Australian first grade cricketwhich turned out to be for the northern districts in Adelaide.
She initially ended her playing career in 2019, but came out of retirement to play a season with The Hundred for Welsh Fire in 2021.